Sulphuric acid (H₂SO₄) Is one of the most widely used and produced industrial chemicals worldwide. It is a strong mineral acid with highly corrosive properties, serving critical roles in chemical manufacturing, energy production, and even forensic science. Due to its reactivity and hazards, it is also regulated as a controlled substance in many regions.
Chemical Identity and Properties
IUPAC Name: Sulfuric acid
Chemical Formula: H₂SO₄
Molecular Weight: 98.08 g/mol
Appearance: Colorless to slightly yellow, oily liquid
Odor: Odorless, but releases irritating fumes when heated
Solubility: Miscible with water (highly exothermic reaction)
Physical and Chemical Characteristics
Property Value
Boiling Point ~337 °C
Melting Point 10.3 °C
Density ~1.84 g/cm³ (at 25 °C)
pKa -3 (very strong acid)
Corrosiveness Highly corrosive to metals and tissues
Reactivity Exothermic with water, reacts violently with organic materials, bases, and oxidizers
Industrial and Laboratory Applications
Sulphuric acid is essential to numerous industries:
Fertilizer production: Manufacturing of phosphate fertilizers
Petroleum refining: Removing impurities in gasoline
Chemical synthesis: Production of nitric acid, hydrochloric acid, dyes, detergents
Batteries: Used in lead-acid car batteries
Metallurgy: Pickling of metals, ore processing
Laboratories: Dehydrating agent, catalyst, analytical reagent
Health Hazards and Toxicology
Sulphuric acid is extremely corrosive, posing significant risks to human health:
Routes of Exposure:
Skin Contact: Causes severe burns, tissue destruction
Eye Contact: Can result in permanent blindness
Inhalation: Fumes can damage the respiratory tract; long-term exposure may cause lung damage
Ingestion: Extremely harmful, causing internal burns and possibly death
Chronic Effects:
Dental erosion (occupational exposure)
Ulceration of respiratory passages
Classified as a Group 1 carcinogen (IARC) when inhaled in mists
Emergency Response: Immediate irrigation with water, remove contaminated clothing, seek urgent medical attention.
Handling, Storage, and Safety
Personal Protective Equipment (PPE): Chemical-resistant gloves, goggles, face shield, acid-resistant lab coat
Storage: In corrosion-resistant containers (e.g., glass or certain plastics), well-ventilated areas, away from water or incompatible substances
Spill Control: Neutralize with sodium bicarbonate or calcium carbonate; avoid water contact during neutralization
Transport: Regulated as a hazardous material (UN 1830 / Class 8)
Legal and Forensic Relevance
Regulated Chemical: Sulphuric acid is a precursor in the manufacture of explosives and narcotics
Controlled in many countries (e.g., under the EU Regulation 2019/1148 on explosive precursors)
Monitored in high-concentration forms due to potential misuse in:
Acid attacks
Homemade explosives (e.g., TATP, nitroglycerin)
Drug synthesis (e.g., extraction in meth labs)
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